Dynamics of endoergic substitution reactions. I. Br+chlorinated aromatic compounds
نویسندگان
چکیده
منابع مشابه
Photosubstitution Reactions of Aromatic Compounds
In nucleophilic aromatic photosubstitution, just as in aromatic substitution in the ground state, substituents can have directing and activating effects. Four rules, which describe orientation of nucleophilic substitution in the excited state, can now be formulated. They are: (a) meta-activation by the nitro group (b) ortho/para-activation by the methoxy group (and probably also by other electr...
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IT sometimes happens in organic chemistry that a large body of related fact accumulates which seemingly cannot be rationalized on the basis of the currently available theoretical concepts. In such circumstances, substantial clarification may often be achieved by an approach which is novel only in application .to the system at band. The pieces of the puzzle may then fall into place and experimen...
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ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 1988
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.455439